Novel 11C-radioisotope method for catalysis study

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Methanol transformations over H-and metal- modified zeolites and MCM-41

ISBN: 365949884X
ISBN 13: 9783659498848
Autor: Sarkadi-Priboczki, Eva
Verlag: LAP LAMBERT Academic Publishing
Umfang: 72 S.
Erscheinungsdatum: 15.12.2013
Auflage: 1/2013
Format: 0.5 x 22 x 15
Gewicht: 125 g
Produktform: Kartoniert
Einband: Kartoniert
Artikelnummer: 5999156 Kategorie:

Beschreibung

The application of radioisotope labeled molecules gives a sensitive detection method to follow adsorption, desorption and catalytic transformations even in co-reaction with non-labeled compounds. This radiolabeling technique was introduced for study of methanol transformation, first on proton and subsequently on Cs, Cu and Fe ion-exchanged aluminosilicates. This novel method was excellent to follow and analyze methanol transformations on different catalysts. The gas chromatographic (GC) analysis was completed with a radiodetector that could distinguish the radiolabeled derivates from other non-radioactive compounds, reagents or impurities. The radio-GC results confirmed the role of acid, basic and redox sites on H- and metal-modified zeolites and MCM-41 catalysts.

Autorenporträt

Institute for Nuclear Research, Hungarian Academy of Sciences (Debrecen,Hungary) Research: Heterogeneous catalysis study by PET isotope and PET imaging Publication: http://www.atomki.hu/p2/authors/aut03497.htm

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