Are ionic liquids actually ionic ones?

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Fluctuational Equation of State and Hypothetical Phase Diagram

ISBN: 3659875694
ISBN 13: 9783659875694
Autor: Rogankov, Vitaly
Verlag: LAP LAMBERT Academic Publishing
Umfang: 272 S.
Erscheinungsdatum: 26.04.2016
Auflage: 1/2016
Format: 1.7 x 22 x 15
Gewicht: 423 g
Produktform: Kartoniert
Einband: Kartoniert
Artikelnummer: 9364820 Kategorie:

Beschreibung

Ionic liquids (ILs) or melting organic salts belong to the special type of fluid thermodynamic systems in which the orthobaric (saturated) vapor phase is practically absent at low (working) temperatures located below the thermal decomposition point. The methodology of FT-(fluctuational thermodynamics) model developed by author and applied to this complicated object (considering by many theoreticians and simulators as an example of ionic fluid behavior) reveals about all typical features of usual neutral systems. In particular, such important for the construction of IL-EOS (equation of state) parameters as the location of virtual critical point, the shape of hypothetical phase diagram and the normal boiling point can be predicted, at least, in the thermodynamically-consistent manner by the proposed FT-approach. The book is recommended for the wide circle of chemists and physicists exploited in their work the remarkable quite useful and often unusual properties of ILs.

Autorenporträt

Vitaly B. Rogankov (69) (Dr. of Phys.-Math. Sci., Prof.). The scientific interests are ranged from the theory of phase transitions and criticality in mixtures up to the study of complex heterophase states in the finite-size systems. Author of about 200 publications and three monographs on the above items. Wife Ann Rogankova (62) and son Oleg (23).

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