Beschreibung
Inhaltsangabe1 Introduction and Fundamental Aspects.- 1.1 Macromolecular Metal Complexes.- 1.2 Types, Formation and Structural Features of MMC.- 1.3 Properties and Application of MMC.- 1.4 Aim of the Book.- 2 Synthesis and Structure of Macromolecular Metal Complexes.- 2.1 Main Structural Principles of Formation and Characteristics of Macromolecular Metal Complexes.- 2.1.1 Classification, Main Requirements and Principles of Macroligands for the Formation of Macromolecular Metal Complexes.- 2.1.1.1 Main Requirements of Macroligands.- 2.1.1.2 Classification of Macroligands.- 2.1.1.3 Methods of Polymer Carrier Functionalization.- 2.1.1.4 Natural Polymers as Macroligands.- 2.1.2 General Principles of MMC Formation.- 2.1.3 Main Approaches for Calculation of Rate Constants of MMC.- 2.1.4 Cooperative Effects During MMC Formation.- 2.1.5 Thermodynamic Description of Macromolecular Metal Complex Formation.- 2.1.6 Main Transformations of Macroligands and Transition Metal Compounds During Complex Formation.- 2.1.7 Methods for Characterization of Composition and Structure of MMC.- 2.2 Type I: Metal Complexes Bound to Macromolecular Carriers via Ligands or Metal Ions.- 2.2.1 Metal Complexes Coordinatively Bound to both Synthetic Organic Polymers and Inorganic Macromolecular Compounds.- 2.2.1.1 MXn Binding with Polyvinylpyridines.- 2.2.1.2 Interaction of MXn with Polyethyleneimine and its Derivates.- 2.2.1.3 MMC Formed by the Use of Oxygen-Containing Donor Centers.- 2.2.1.4 Macrocomplexes with Phosphorous-Containing Ligands.- 2.2.1.5 Sulfur-Containing Macroligands in Coordination Reactions.- 2.2.1.6 Metal Complexes Coordinatively Bound to Synthetic Inorganic Macromolecular Compounds.- 2.2.2 Metal Complexes Covalently and Ionically Bound to Synthetic and Inorganic Macromolecular Compounds.- 2.2.2.1 Specific Features of MXn Binding with Polyvinyl Alcohol.- 2.2.2.2 MMC Derived from Polyacids.- 2.2.2.3 Transition Metal Ions Binding with Polyamino Acids.- 2.2.2.4 Covalent Binding with Inorganic Ligands.- 2.2.3 Macromolecular Metal Chelates.- 2.2.3.1 Molecular Metal Chelates.- 2.2.3.2 Intracomplex Compounds.- 2.2.3.3 MMCh as Macrocyclic Complexes.- 2.2.3.4 Interpolymer Metal Chelates.- 2.2.3.5 Metal Chelates on the Surface of Oxides and Mixed-Type Polymers.- 2.2.4 Polymeric ?-Complexes of Transition Metal Ions.- 2.2.5 Macrocomplexes with Natural Polymers.- 2.2.6 Polymerization and Copolymerization of Metal-Containing Monomers as a Way for MMC Synthesis.- 2.3 Type II: Metal Complexes and Metals as Part of a Polymer Chain or Network.- 2.3.1 Ligand of a Metal Complex as Part of a Polymer Chain or Network (Polymeric Metal Complexes).- 2.3.1.1 Noncyclic Organic Ligands.- 2.3.1.2 Cyclic Organic Ligands.- 2.3.2 Ligand and Metal as Part of a Polymer Chain or Network (Metal Coordination Polymers).- 2.3.2.1 Inorganic Coordination Polymers.- 2.3.2.2 Organic Coordination Polymers.- 2.3.3 Homochain Polymers with Covalent Bonds Between Metals (Homometallic Polymers).- 2.3.4 Heterochain Polymers with Covalent Bonds Between Metals and Another Element (Heterometallic Polymers).- 2.3.5 Cofacial Stacked Polymeric Metal Complexes.- 2.3.5.1 Covalent/Covalent Bonds Between Central Metal Ions.- 2.3.5.2 Covalent/Coordinative Bonds Between Central Metal Ions.- 2.3.5.3 Coordinative/Coordinative Bonds Between Central Metal Ions.- 2.3.5.4 Self-Organization, Discotic Crystalline Liquids.- 2.3.6 Metallocenes as Part of a Polymer Chain (Polymetallocenes).- 2.4 Type III: Metal Complexes, Zero-Valent Metals and Metal Clusters Physically Connected with Macromolecular Compounds.- 2.4.1 Combination with Organic Polymers.- 2.4.1.1 Metal Complexes.- 2.4.1.2 Metal Clusters.- 2.4.2 Combination with Inorganic High Molecular Systems.- 2.4.2.1 Metal Complexes.- 2.4.2.2 Metal Clusters.- 3 Polymer Metal Complexes in Living Systems.- 3.1 Introduction.- 3.2 Overview of Ligands Present in Living Systems.- 3.2.1 General Coordination of Behaviour of Ligands.- 3.2.2 Systematic Overview of Ligands that Bind to
