Modern Crystallography III

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181,89 

Crystal Growth, Springer Series in Solid-State Sciences 36

ISBN: 3642818374
ISBN 13: 9783642818370
Autor: Chernov, A A
Verlag: Springer Verlag GmbH
Umfang: xx, 517 S.
Erscheinungsdatum: 08.12.2011
Auflage: 1/2011
Produktform: Kartoniert
Einband: Kartoniert

Inhaltsangabe1: Crystallization Processes.- 1 Equilibrium.- 1.1 Phase Equilibrium.- 1.1.1 One-Component Systems.- 1.1.2 Multicomponent Systems.- 1.1.3 Crystallization Pressure.- 1.2 Surface Energy and Periodic Bond Chains.- 1.2.1 Surface Energy.- 1.2.2 Periodic Bond Chains and Estimates of the Surface Energy.- 1.2.3 Surface Energy Anisotropy.- 1.3 Atomic Structure of the Surface.- 1.3.1 Surface Configurations and Their Energies.- 1.3.2 Adsorption Layer.- 1.3.3 Step Roughness.- 1.3.4 Surface Roughness.- 1.4 Phase Equilibrium with Allowance for Surface Energy. Equilibrium Shape of a Crystal.- 1.4.1 Phase Equilibrium over a Curved Surface.- 1.4.2 Equilibrium Shape of a Crystal.- 1.4.3 Average Detachment Work. Finding Faces of Equilibrium Shape.- 1.4.4 Experimental Observation of an Equilibrium Shape.- 2 Nucleation and Epitaxy.- 2.1 Homogeneous Nucleation.- 2.1.1 Work and Rate of Nucleation. Size and Shape of Nuclei.- 2.1.2 Critical Supersaturation and Metastability Boundary in Vapors.- 2.1.3 Nucleation in Condensed Phases.- 2.1.4 Transient Nucleation Processes.- 2.2 Heterogeneous Nucleation.- 2.2.1 Work and Rate of Nucleation. Size and Shape of Nuclei.- 2.2.2 Atomistic Picture of Nucleation. Clusters.- 2.2.3 Decoration. Initial Stages of Growth.- 2.2.4 Activity of Solid Surfaces in Melts.- 2.3 Epitaxy.- 2.3.1 Principal Manifestations.- 2.3.2 Thermodynamics.- 2.3.3 Kinetics.- 2.3.4 Misfit Dislocations and the Conditions of Pseudomorphism.- 3 Growth Mechanisms.- 3.1 Normal and Layer Growth of Crystals.- 3.1.1 Conditions of Normal and Layer Growth.- 3.1.2 Kinetic Coefficients in Normal Growth.- 3.1.3 Layer Growth and the Anisotropy of the Surface Growth Rate.- 3.2 Layer Growth in Different Phases.- 3.2.1 Growth from Vapor.- 3.2.2 Growth from Solution.- 3.2.3 Growth from the Melt.- 3.3 Layer Sources and Face Growth Rates.- 3.3.1 Nuclei.- 3.3.2 Dislocations.- 3.3.3 Kinetic Coefficient and Anisotropy of Face Growth.- 3.3.4 Experimental Data on Layer Sources.- 3.4 Morphology of a Surface Growing Layerwise.- 3.4.1 Optical Methods Used to Investigate Growth Processes and Surfaces.- 3.4.2 Steps, Vicinal Hillocks, and the Formation of Dislocations During Vapor Growth.- 3.4.3 Kinematic Waves and Macrosteps.- 3.4.4 Surface Melting.- 4 Impurities.- 4.1 Effect of Impurities on Growth Processes.- 4.1.1 Thermodynamics and Structure of Solutions.- 4.1.2 Adsorption.- 4.1.3 Dependences of Growth and Morphology on the Concentration of Impurities.- 4.2 Trapping of Impurities: Classification and Thermodynamics.- 4.2.1 Classification.- 4.2.2 Thermodynamics.- 4.2.3 Equilibrium Impurity Distribution in a Crystal-Melt System.- 4.2.4 Equilibrium Impurity Distribution in a Crystal-Solution System.- 4.2.5 Equilibrium in the Surface Layer.- 4.2.6 Mutual Effects of Impurity Particles.- 4.3 Trapping of Impurities: Kinetics.- 4.3.1 Surface Processes.- a) Statistical Selection.- b) Diffusional Relaxation.- c) Sectorial Structure.- d) Vicinal Sectoriality.- e) Rapid Diffusionless Crystallization.- 4.3.2 Pulse Annealing.- 4.3.3 Diffusion in the Mother Medium.- 4.3.4 Observed Distribution Coefficients.- 5 Mass and Heat Transport. Growth Shapes and Their Stability.- 5.1 Mass and Heat Transfer in Crystallization.- 5.1.1 Stagnant Solution. Kinetic and Diffusion Regimes.- 5.1.2 Stirred Solution. Summation of Resistances.- 5.1.3 Kinetic and Diffusion Regimes in the Melt.- 5.1.4 Diffusion Field of a Polyhedron.- 5.2 Growth Shapes.- 5.2.1 Kinematics.- 5.2.2 Determination of Crystal Habit by the PBC Method.- 5.2.3 The Bravais-Donnay-Harker Rule.- 5.2.4 Effect of Growth Conditions.- 5.2.5 Faceting Effect.- 5.3 Stability of Growth Shapes.- 5.3.1 Sphere.- 5.3.2 Polyhedron.- 5.3.3 Plane.- 6 Creation of Defects.- 6.1 Inclusions.- 6.1.1 Inclusions of the Mother Liquor.- 6.1.2 Inclusions of Foreign Particles.- 6.2 Dislocations, Internal Stresses and Grain Boundaries.- 6.2.1 Dislocations from a Seed.- 6.2.2 Creation of Dislocations in Surface Processes.- 6.2.3 Orientation of Dislocations.- 6.2.

Artikelnummer: 4379841 Kategorie:

Beschreibung

Early in this century, the newly discovered x-ray diffraction by crystals made a complete change in crystallography and in the whole science of the atomic structure of matter, thus giving a new impetus to the development of solid-state physics. Crystallographic methods, pri­ marily x-ray diffraction analysis, penetrated into materials sciences, mol­ ecular physics, and chemistry, and also into many other branches of science. Later, electron and neutron diffraction structure analyses be­ came important since they not only complement x-ray data, but also supply new information on the atomic and the real structure of crystals. Electron microscopy and other modern methods of investigating mat­ ter-optical, electronic paramagnetic, nuclear magnetic, and other res­ onance techniques-yield a large amount of information on the atomic, electronic, and real crystal structures. Crystal physics has also undergone vigorous development. Many re­ markable phenomena have been discovered in crystals and then found various practical applications. Other important factors promoting the development of crystallog­ raphy were the elaboration of the theory of crystal growth (which brought crystallography closer to thermodynamics and physical chem­ istry) and the development of the various methods of growing synthetic crystals dictated by practical needs. Man-made crystals became increas­ ingly important for physical investigations, and they rapidly invaded technology. The production. of synthetic crystals made a tremendous impact on the traditional branches: the mechanical treatment of mate­ rials, precision instrument making, and the jewelry industry.

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