Dipolar Correlation Spectroscopy

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Higher-Order Correlation Terms in Three-Spin Double Electron-Electron Resonance (DEER), BestMasters

ISBN: 3658091908
ISBN 13: 9783658091903
Autor: Basel, Bettina
Verlag: Springer Spektrum
Umfang: xxix, 116 S., 98 s/w Illustr., 116 p. 98 illus.
Erscheinungsdatum: 16.03.2015
Auflage: 1/2015
Produktform: Kartoniert
Einband: Kartoniert

Bettina Basel presents experimental conditions which allow to extract the three-spin contribution precisely from experimental multi-spin double electron-electron resonance (DEER) signals. The theory and concepts behind the used techniques, which are among others broadband chirp pump pulses, overcoupling of microwave resonators and echo reduction measurements, are discussed and explained in detail. Moreover the setup and results of DEER experiments with newly introduced double chirp pump pulses consisting of two separate chirps are shown. Particular attention is paid to the phenomenon of orientation selection and the concept of orthogonal spin labeling.Contents – DEER with Chirp and Double Chirp Pump Pulses Coupling of the Resonator and Determination of Its Resonance Profiles Gd(III)Nitroxide DEER Echo Reduction Measurements  Target Groups – Researchers and students of physical chemistry, biophysics, and chemical physics Practitioners within the field of Pulse EPR  The AuthorBettina Basel received her master’s degree in chemistry at Friedrich-Alexander University in Erlangen. Her master’s thesis was written during an ERASMUS stay at ETH Zurich under the supervision of Prof. Dr. Gunnar Jeschke.

Artikelnummer: 7847226 Kategorie:

Beschreibung

Bettina Basel presents experimental conditions which allow to extract the three-spin contribution precisely from experimental multi-spin double electron-electron resonance (DEER) signals. The theory and concepts behind the used techniques, which are among others broadband chirp pump pulses, overcoupling of microwave resonators and echo reduction measurements, are discussed and explained in detail. Moreover the setup and results of DEER experiments with newly introduced double chirp pump pulses consisting of two separate chirps are shown. Particular attention is paid to the phenomenon of orientation selection and the concept of orthogonal spin labeling.

Autorenporträt

Bettina Basel received her masters degree in chemistry at Friedrich-Alexander University in Erlangen. Her masters thesis was written during an ERASMUS stay at ETH Zurich under the supervision of Prof. Dr. Gunnar Jeschke.

Herstellerkennzeichnung:


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E-Mail: juergen.hartmann@springer.com

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